Standard Practice for Development and Validation of Multivariate Analyses for Use in Predicting Properties of Petroleum Products, Liquid Fuels, and Lubricants based on Spectroscopic Measurements

Importancia y uso:

5.1 This practice can be used to establish the validity of the results obtained by an infrared (IR) spectrophotometer or Raman spectrometer at the time the calibration is developed. The ongoing validation of PPTMRs produced by analysis of unknown samples using the multivariate model is covered separately (see for example, Practice D6122).

5.2 The multivariate calibration procedures define the range over which measurements are valid and demonstrate whether the accuracy and precision of the analysis outputs meet user requirements.

5.3 This practice describes sampling procedures that must be followed to ensure that the sample which is analyzed by the spectrophotometer or spectrometer is the same as the sample analyzed by the PTM. The sampling procedures apply to analyses done on lab analyzers, at-line analyzers, and online analyzers.

Subcomité:

D02.25

Referida por:

D7861-24, D5845-21, D5845-21, E2412-23A, E2412-23A, D5845-21, D8554-24A, D7278-21, D7825-24, D7861-24, D8340-22, E2412-23A, D8470-22, D3764-23, D7235-21A, D3764-23, D6122-25

Volúmen:

05.05

Número ICS:

75.080 (Petroleum products in general)

Palabras clave:

multivariate analysis; outlier decision; spectroscopic analysis; spectroscopic process analyzer;