Standard Guide for High Temperature Strength Measurements of Graphite Impregnated with Molten Salt

Importancia y uso:

5.1 The Molten Salt Reactor is a nuclear reactor which uses graphite as reflector and structural material, and molten salt as coolant. The graphite components will be submerged in the molten salt during the lifetime of the reactor. The porous structure of graphite may lead to molten salt permeation, which can affect the thermal and mechanical properties of graphite. Consequently, it may be necessary to measure the various strengths of the manufactured graphite materials after impregnation with molten salt and before exposure to the reactor environment in a range of test configurations in order for designers or operators to assess their performance.

Note 1: Depending upon the salt selected for the reactor, there may be some chemical reaction between the salt and the graphite that could affect properties. The user should establish, prior to following this guide, that any interactions between the molten salt and graphite are understood and any implications for the validity of the strength tests have been assessed.

5.2 For gas-cooled reactors, the strength of a graphite specimen is usually measured at room temperature. However, for molten salt reactors, the operating temperature of the reactor must be higher than the melting temperature of the salt, and so the salt will be in solid state at room temperature. Consequently, room temperature measurements may not be representative of the performance of the material at its true operating conditions. It is therefore necessary to measure the strength at an elevated temperature where the salt is in liquid form.

Note 2: Users should be aware that a small increase in graphite strength is expected with increasing temperature. Testing at the plant operating temperature will eliminate this small uncertainty.

5.3 The purpose of this guide is to provide considerations, which should be included in testing graphite specimens impregnated with molten salt at elevated temperature.

5.4 For the test results to be meaningful, the test material must have been impregnated at the reactor operating temperature of interest and the strength measurement conducted at the same temperature following this guide. The user must consider the effect of interaction between graphite and impregnated salt on the representativeness of the strength test based upon the heating and cooling stages between impregnation and testing.

Note 3: The user may wish to measure the strength of the same test geometry on unimpregnated graphite both at room temperature and at the chosen elevated temperature as a benchmark prior to the testing of the impregnated material.

Note 4: The user may wish to demonstrate that the impregnated test specimen does not lose molten salt during the elevated strength test procedure. This should be performed by putting the impregnated specimen through the exact procedure (temperature and duration) without applying any test load, weighing the specimen before and after the procedure. A reduction in mass will indicate loss of molten salt and the user will then need to assess its significance.

Subcomité:

D02.F0

Volúmen:

05.05

Número ICS:

27.120.10 (Reactor engineering), 27.120.30 (Fissile materials and nuclear fuel technology), 71.060.10 (Chemical elements)

Palabras clave:

elevated temperature; graphite; molten salt; strength;